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5�? [13][14][15], Except where otherwise noted, data are given for materials in their, ChemIDplus - 7447-41-8 - KWGKDLIKAYFUFQ-UHFFFAOYSA-M - Lithium chloride - Similar structures search, synonyms, formulas, resource links, and other chemical information, Ullmann's Encyclopedia of Industrial Chemistry, "Large-scale preparation of graphene by high temperature insertion of hydrogen into graphite", "Lithium chloride effectively kills the honey bee parasite, https://en.wikipedia.org/w/index.php?title=Lithium_chloride&oldid=996316359, Chemical articles with multiple compound IDs, Multiple chemicals in an infobox that need indexing, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, R. Vatassery, titration analysis of LiCl, sat'd in Ethanol by AgNO, This page was last edited on 25 December 2020, at 21:15. Lithium chloride is a chemical compound with the formula LiCl. 1956]. MDL number MFCD00011078. MSDS-0002 Rev. Boron trifluoride reacts with incandescence when heated with lithium [Merck 11th ed. In developing Xenopus embryos, lithium chloride is observed to exert inhibition of GSK-3β (glycogen synthase kinase-3β), yet not reported to be a general inhibitor of other protein kinases. Sore throat. Causes redness and pain. Info. : 7447-41-8 Molecular Weight: 42.39 Chemical Formula: LiCl Product Codes: J.T. ��c��}��M�(�Ohv�-ʿ (�s�
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It is used as a desiccant for drying air streams. The percent relative humidity at 25 °C (77 °F) can be estimated, with minimal error in the range 10–30 °C (50–86 °F), from the following first order equation: RH=107.93-2.11C, where C is solution LiCl concentration, percent by mass. New Reagents for Selective Metalation, Deprotonation, and 1,2-Additions. eCl@ss 38050203 . Shortness of breath. Potential Health Effect Eye: Causes moderate eye irritation. >V��DUg_?�ٴ�ӯu����Uq�Y ���-�:���X���%�u8�{Y}�����������s��ގ�vfY��o ���MB͊���Z�
�uH�Ь�J?�/���mP8��1���4gR:͙�L��(Mj���P�s�lO��h5�枠8:=>���N��&%��+��|������Zxku|��M>FH,c`�X�`��. Section 1: Chemical Product and Company Identification. Flush eyes with running water for at least 15 minutes, keeping eyelids open. (lithium, thionyl chloride) are considered hazardous under US OSHA and are subject to the requirements of 29 CFR 1200 Hazard Communication.. Lithium Battery Safety With proper use and handling, lithium batteries have demonstrated an excellent safety record. No envisaged effects other than acute effects from local irritation [��
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�S��{�U Lithium (Li) OSHA PEL N/A ACGIH TLV Not established Thionyl Chloride Aluminum Chloride (AlCl3) 1.0 ppm (4.9 3mg/m ) 2 3mg/m 1.0 ppm (4.9 3mg/m ) 2 mg/m3 Lithium Chloride Not established Not established SECTION 3 - Hazards Identification **DANGER** INTERNAL CONTENTS ARE EXTREMELY HAZARDOUS. [11], Lithium chloride has been shown to have strong acaricidal properties, being effective against Varroa destructor in populations of honey bees. Severe deep burns. Cough. }�,@����)�����H �` E0�
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Burning sensation. [7] The anhydrous salt can be regenerated by heating the hydrates. It is used as a dessicant. PubChem Substance ID 24852187. Lithium Thionyl Chloride Battery Safety Data Sheet 3 May 2017 EN (English) 5/7 Aspiration hazard : Not classified Symptoms/effects after inhalation : Not expected to present a significant inhalation hazard under anticipated conditions of normal use. Treatment with Pamelor could be resumed 24 hours after the last dose of linezolid or intravenous methylene blue (see WARNINGS). Lithium Coupon. Also, in biochemical applications, it can be used to precipitate RNA from cellular extracts.[8]. Effects of exposure to Lithium: Fire: Flammable. The salt is a typical ionic compound (with certain covalent characters) , although the small size of the Li ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties. Chlorine vapors and lithium react producing a luminous flame [Mellor 2, Supp. [5] Anhydrous LiCl is prepared from the hydrate by heating with a stream of hydrogen chloride. ACUTE/CHRONIC HAZARDS: This compound is a mild irritant. Many reactions may cause fire or explosion. Ingestion: Abdominal cramps. [12], Lithium salts affect the central nervous system in a variety of ways. 1. The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). Lithium chloride SDS Safety Data Sheet for Lithium chloride 105679. N… Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. ��0�����X�D��Ai��G���ʄQ�fW��v[N�DN1���@� -L����>��anl®i�1S��{�䆬�2�Vo +�#��R\&�KᙱD��Kv
��6,m��@�[��6�Lp�!��"� ix�:�r�m1���rվ�h�yM���b�U'Cɮy]4���g�P���R�N�:�Գ���X���O���x�E)���� Lithium chloride is a chemical compound with the formula LiCl. Inhalation: Burning sensation. Lithium chloride CAS 7447-41-8 for analysis EMSURE® ACS,Reag. words matched: chloride, Lithium SRA028 – Rainbow flames Alcohol is added to a series of beakers or crystallizing dishes containing metal salts and boric acid. Skin burns. LiCl also absorbs up to four equivalents of ammonia/mol. Lithium Battery Safety With proper use and handling, lithium batteries have demonstrated an excellent safety record. Lithium chloride has been extensively tested for REACH registration Acute Effects From Overexposure: No data available for the formulation. Linear Formula LiCl . It is not toxic by ingestion, but by its corrosive nature can be irritating to the skin and eyes, it can also irritate the nostrils (National Institute for Occupational Safety and Health, 2015). The salt forms crystalline hydrates, unlike the other alkali metal chlorides. SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. CAS#: 7447-41-8. 402 0 obj
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Maleic anhydride decomposes explosively in the presence of lithium [Chemical Safety Data Sheet SD-88. Fires may be fought but only from safe fire fighting distance, evacuate all persons from immediate area of fire. 5.4 Further information No data available. The salt is a typical ionic compound (with certain covalent characters) , although the small size of the Li+ ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties.[5]. Material Safety Data Sheet Lithium chloride MSDS Section 1: Chemical Product and Company Identification Product Name: Lithium chloride Catalog Codes: SLL1366 CAS#: 7447-41-8 RTECS: OJ5950000 TSCA: TSCA 8(b) inventory: Lithium chloride CI#: Not available. H�̗Mk�@�����jG�o9d������B���/�@Ӕ���^���M֘���k�<3�����,N��������ԕ���F�ÇWu%����G1z�����Hp]W�����`�1uW.t�1M�i�[�� c��14��1]��ki;K�A~��Ur��L��vZ�s�=�P>�m
:�YWA���at. Jr,XH�Q��ƻ/�W�JJ���]�p��="�'�����!�jl��x��tI�G����.�E����EN�>�+J�;P�YF�T��|$��{()F%����{E���[ Y �f{BC�@تݯ5��jG�i��="�! Molecular Weight 42.39 . 1:380. Lithium Chloride No exposure limit established No exposure limit established Appropriate Engineering Controls : Whenever possible the use of local exhaust ventilation or other engineering controls is the preferred method of controlling exposure to airborne dust … Dehydration, weight loss, slurred speech, blurred vision, sensory loss, ataxia (failure of muscular coordination), tremors, and convulsions may occur. F3��-�5�"���:܂���.u�N�m�
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l�;� �ü�,���8�8�:��H�} One instance of reversible noticeable hepatotoxicity has been reported. lithium chloride. 3 Effective date : 10.24.2014 Page 2 of 7 Lithium Chloride, Reagent Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Section 3: Hazards Identification. Product Identification Synonyms: Lithium monochloride CAS No. LiCl is also used as a brazing flux for aluminium in automobile parts. [5] In more specialized applications, lithium chloride finds some use in organic synthesis, e.g., as an additive in the Stille reaction. 5.2 Special hazards arising from the substance or mixture Hydrogen chloride gas, Lithium oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. This deliquescent salt forms a self-solution when exposed to air. Lithium chloride is also used as a flame colorant to produce dark red flames. Pain. Haz. Lithium chloride, anhydrous Revision Date 18-Jan-2018 Autoignition Temperature Explosion Limits Upper No data available Lower No data available Sensitivity to Mechanical ImpactNo information available Sensitivity to Static DischargeNo information available Specific Hazards Arising … ;(Q�c+�Z�JY��V���'"�7�XJ˵��p���d~��Mt�R~���ˈY�Z>���&o�ә�9j8|��k8|��إ�s.�lw��;��h}4ҳ�Y���L`��1��ʧ��gm�_6��g����٢C�l=���8yv� ���d��%��S?�+�#�,�3�2���=JLi��w! LEAKING FLUID IS CORROSIVE. safety hazards of Copper Chloride to potentially exposed workers. Gives off irritating or toxic fumes (or gases) in a fire. As with any other ionic chloride, solutions of lithium chloride can serve as a source of chloride ion, e.g., forming a precipitate upon treatment with silver nitrate: Lithium chloride is produced by treatment of lithium carbonate with hydrochloric acid. �%��U��M�y�!K�^��5�¼�AOe��Süupk�w�Ƽ{"�Y��w�߷�浫���S/����J �('��X˘��P���� �C�T�� ��8w+���xq|.�2��"��#c�(HZ���G�S�|��N*�;� LITHIUM CHLORIDE . Laboured breathing. Skin: Redness. Product Name: Lithium chloride. 7447-41-8 Lithium chloride min 99% 231-212-3 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful in contact with skin and if swallowed. Lithium chloride 7447-41-8X -231-212-3X X XXKE-22552 U.S. Federal Regulations SARA 313 Not applicable SARA 311/312 Hazard CategoriesSee section 2 for more information CWA (Clean Water Act) Not applicable Clean Air Act Not applicable OSHA - Occupational Safety and Health Administration Not applicable CERCLA Not applicable %PDF-1.6
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